21st International Congress of Chemical and Process Engineering CHISA 2014 Prague
17th Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction PRES 2014
23-27 August 2014 Prague, Czech Republic

Lectures A

A1 - Sunday morning
Reaction engineering, catalysis and kinetics

Reactor design and intensification

Chairpersons: J. Kosek, K. R. Rout

A1.3   11:00   Thermo Gravimetric Analyzer (TGA) fixed-bed reactor to study the kinetics of CO2 capture with solid sorbent. *K. R. Rout, J. Meyer1, A. Norheim2, H. A. Jakobsen (NTNU, Trondheim, NO; 1IFE, Oslo, NO; 2ZEG Power AS, Oslo, NO) [267] Abstract

A1.4   11:20   Dynamic non isothermal trickle bed reactor with both internal diffusion and heat conduction: arabinose hydrogenation as a case study. *V. Russo, T. Kilpiö1, M. Di Serio, R. Tesser, E. Santacesaria, T. Salmi1 (Univ. Napoli Federico II, IT; 1Abo Akad. Univ., Turku, FI) [381] Abstract

A1.5   11:40   Residence time distribution in an inclined rotating fixed-bed reactor. *H.-U. Härting, R. Lange1, M. Schubert (Helmholtz-Zentrum Dresden-Rossendorf, DE; 1Tech. Univ., Dresden, DE) [1022] Abstract

A1.6   12:00   Study and modelling of a catalytic heterogeneous esterification process. *E. Schaer, A. Vonner, C. Castel, A. Moreliere1, L. Debiais1, S. Tretjak1 (Univ. Lorraine, Nancy, FR; 1Arkema, Saint Avold, FR) [1294] Abstract

A2 - Sunday afternoon
Reaction engineering, catalysis and kinetics

Mathematical modeling of reaction and transport processes

Chairpersons: L. Kaluža, T. Salmi

A2.1   14:00   Keynote lecture: A new general model for reactive solid particles. *T. Salmi, J. Wärnå, D. Murzin, H. Grénman (Abo Akad. Univ., Turku, FI) [863] Abstract

A2.2   14:40   Morphogenesis predictions in reactive polymer blends. *M. Vonka, J. Kosek (Inst. Chem. Technol., Praha, CZ) [1153] Abstract

A2.3   15:00   CFD hydrodynamic simulation coupled with mass and energy in a TBR incorporating the pellet microstructure through transport coefficients. *M. E. Cordero, L. G. Zarate Lopez, R. Natividad1, J. A. Hernandez-Servin2 (Univ. Pop. Aut. Est. Puebla, Barrio Santiago, MX; 1UAEM-UNAM. Toluca, MX; 2Univ. Aut. Mex., Toluca, MX) [569] Abstract

15:20   Coffee break, poster session

A2.4   16:20   Software for simulation of second generation ethanol production by SSF process. *M. B. Silva, L. M. Inácio (Fed. Univ. Triangulo Mineiro, Uberaba, BR) [776] Abstract

A2.5   16:40   Utilization of semi-mechanistic steam-cracking model. *A. Karaba1, P. Zamostny, Z. Bělohlav, J. Lederer1, T. Herink2 (Inst. Chem. Technol., Praha, CZ; 1Res. Inst. Inorg. Chem., Usti n/L, CZ; 2Unipetrol RPA, Litvínov, CZ) [987] Abstract

A2.6   17:00   Ethane and propane pyrolysis in experimental setup with additional radicals’ generation. *V. N. Snytnikov, V. N. Snytnikov, N. S. Masyuk, A. V. Nekrasov (Boreskov Inst. Catal., Novosibirsk, RU) [641] Abstract

A3 - Monday morning
Reaction engineering, catalysis and kinetics

Biomass to chemicals

Chairpersons: P. U. Foscolo, M. Marek

A3.3   11:00   Oxygen transport by ionic membranes: correlation of permeation data and prediction of char burning in a membrane-assisted biomass gasification process. T. Antonini, V. Anzoletti, K. Gallucci, *P. U. Foscolo (Univ. l'Aquila, IT) [115] Abstract

A3.4   11:20   Epoxidation of vegetable oils in a semibatch reactor: kinetics and reactor modelling. P. Tolvanen, *J. Wärnå, K. Eränen, T. Salmi (Abo Akad. Univ., Turku, FI) [366] Abstract

A3.5   11:40   Two-step and simultaneous direct liquefaction and hydrodeoxygenation of lignocellulosic biomass by imidazolium ionic liquids and NiMo/Al2O3 catalyst. *M. Grilc, B. Likozar1, J. Levec1 (Nat. Inst. Chem., Ljubljana, SI; 1Univ. Ljubljana, SI) [495] Abstract

A3.6   12:00   Mechanism and kinetic studies on the synthesis of glyceraldehyde via anodic oxidation of glycerol. *J. C. Beltrán-Prieto, R. Slavík, K. Kolomazník, J. Pecha (T. Bata Univ., Zlín, CZ) [694] Abstract

A3.7   12:20   Kinetics study of triglyceride transesterification catalyzed by tetramethylammonium hydroxide (TMAH). *J. Pecha, L. Šánek, K. Kolomazník (T. Bata Univ., Zlín, CZ) [1245] Abstract

A4 - Monday afternoon
Reaction engineering, catalysis and kinetics

Green processes

Chairpersons: B. Heinrichs, L. M. Gómez-Sainero

A4.1   14:00   Modelling the green way of starch modification in semibatch reactor – two-stage kinetics and mass transfer. *P. Tolvanen, J. Wärnå, D. Y. Murzin, T. Salmi (Abo Akad. Univ., Turku, FI) [191] Abstract

A4.2   14:20   Production of hydrocarbons by catalytic hydrodechlorination of chloroform. *L. M. Gómez-Sainero, M. Martin-Martinez, M. A. Alvarez-Montero, J. Bedia, A. Arevalo-Bastante, J. J. Rodriguez (Univ. Auton., Madrid, ES) [308] Abstract

A4.3   14:40   Al2O3-TiO2-Ag: a new bactericidal material designed in a fixed bed reactor for continuous spa water disinfection. *M.-A. Tartanson, L. Soussan, M. Rivallin, C. Chis1, C. Faur (Univ. Montpellier 2, FR; 1CARDPool Co., Ales, FR) [359] Abstract

A4.4   15:00   Reduction of water pollution through photocatalysis over a Zn2+ doped TiO2 catalyst prepared from aqueous sol-gel process – A kinetic study. C. M. Malengreaux, S. L. Pirard, J. R. Bartlett1, *B. Heinrichs (Univ. Liege, BE; 1Univ. Sunshine Coast, Marochydore DC, AU) [756] Abstract

15:20   Coffee break, poster session

A4.5   16:20   Catalytic wet oxidation of aniline using persulfate ion as an oxidizing agent. *V. Nikitenko, A. Brenner, M. V. Landau (Ben-Gurion Univ. Negev, Beer-Sheva, IL) [566] Abstract

A4.6   16:40   Synthesis of N-codoped TiO2 via sonochemical method for degradation of CI Reactive Black 5. *C. Y. Teh, T. Y. Wu, C. W. H. Yab (Monash Univ., Selangor, MY) [797] Abstract

A4.7   17:00   Strategies for minimizing N2O emissions during the regeneration of NOx storage catalyst. *D. Mráček, P. Kočí, M. Marek, J.-S. Choi1, J. Pihl1, W. P. Partridge1 (Inst. Chem. Technol., Praha, CZ; 1Oak Ridge Nat. Lab., Knoxville TN, US) [847] Abstract

A4.8   17:20   Intensification of paracetamol degradation by sono-Fenton process. G. Cruz-González, K. González-Labrada1, U. J. Jaúregui-Haza, *J. Ramírez-Muñoz, J. A. Colin-Luna2 (Inst. Sup.Tec. Cienc. Apl., La Habana, CU; 1Inst. Sup. Politec., La Habana, CU; 2Univ. Aut. Metrop., Ascapotzalco, MX) [1415] Abstract

A5 - Tuesday morning
Reaction engineering, catalysis and kinetics

Technology development for reaction processes

Chairpersons: P. Biasi, B. Saha

A5.1     8:30   Keynote lecture: Tailoring the process of H2O2 direct synthesis: catalyst design and reaction engineering to reach an industrial feasibility. *P. Biasi, T. Salmi1, J.-P. Mikkola1 (Umea Univ., SE; 1Abo Akad. Univ., Turku, FI) [1065] Abstract

A5.2     9:10   Kinetics of hydrodesulphurization process–sulphur removing from heterocyclic aromatic compounds in gas oil. *A. Prokešová, V. Tukač, A. Vráblík1, M. Zbuzek1, R. Černý1 (Inst. Chem. Technol., Praha, CZ; 1Res. Inst. Inorg. Chem., Litvínov, CZ) [135] Abstract

A5.3     9:30   Influence of temperature and space velocity (WHSV) on the hydrodesulphurization of Scrap Tire Pyrolysis Oil (STPO) on an alumina-supported NiMo catalyst. I. Hita, *E. Rodríguez, A. Gutiérrez, G. Lopez, J. M. Arandes, P. Castaño (Univ. Pais Vasco, Bilbao, ES) [332] Abstract

A5.4     9:50   Gas phase synthesis of isopropyl chloride from isopropanol and HCl over alumina catalysts. *N. Bukhanko, W. Larsson, A. Samikannu, J. Wärnå1, J.-P. Mikkola1 (Umea Univ., SE; 1Abo Akad. Univ., Turku, FI) [1201] Abstract

A5.5   10:10   The commercial development of new to the world “Bromine Index reduction technology for benzene feedstock”. *K. Suriye, W. Tanthapanichakoon (SGC Chemicals, Bangkok, TH) [1297] Abstract

10:30   Coffee break, poster session

A5.6   11:00   Keynote lecture: A safer and scalable continuous alkene epoxidation process. M. L. Mohammed, D. Patel, R. Mbeleck, D. C. Sherrington1, *B. Saha (London South Bank Univ., UK; 1Univ. Strathclyde, Glasgow, UK) [500] Abstract

A5.7   11:40   Production of 1-propanol from propionic acid via hydrogenation of ethyl propionate. H. P. Dwiyasni, *R. Muthia, J. Oltvoort, A. Segins, A. G. J. van der Ham, H. van den Berg (Twente Univ., Enschede, NL) [307] Abstract

A5.8   12:00   Redox activity and stability of NiO-based oxygen transfer materials for sorption enhanced chemical looping steam methane reforming. L. Silvester, E. Heracleous1, A. Antzara2, A. A. Lemonidou2, *D. B. Bukur (Texas A&M Univ. at Qatar, Doha, QA; 1Chem. Proc. Eng. Res. Inst., Thessaloniki, GR; 2Aristotle Univ., Thessaloniki, GR) [752] Abstract

A5.9   12:20   An experimental investigation on oxidative desulfurization of gas condensate. *M. Bazmi, M. Ghaedian, A. Shafeghat (Res. Inst. Pet. Ind., Tehran, IR) [1194] Abstract

A6 - Tuesday afternoon
Reaction engineering, catalysis and kinetics

Chairpersons: H. Gruber-Woelfler, A. Muramatsu

A6.1   14:00   Keynote lecture: Engineering the environment of dispersed nanoparticle catalysts for enhanced activities at a molecular level. P. J. Dyson (EPFL, Lausanne, CH) [1075] Abstract

A6.2   14:40   Accelerated determination of long-term activity and relation between physic-chemical structure and activity of aged hydrodesulphurization catalysts. *M. Zbuzek, A. Vráblík, R. Černý, V. Tukač1, A. Prokešová1 (Res. Inst. Inorg. Chem., Litvínov, CZ; 1Inst. Chem. Technol., Praha, CZ) [82] Abstract

A6.3   15:00   Highly loaded carbon black supported Pt catalysts for fuel cells. *L. Kaluža, M. Zdražil, D. Gulková, Z. Vít, O. Šolcová, K. Soukup, L. Maixnerová (Inst. Chem. Proc. Fundam., Praha, CZ) [109] Abstract

15:20   Coffee break, poster session

A6.4   16:20   Well-defined MFI-type zeolite and their DTO catalytic activity. H. Kobayashi, M. Nakaya, K. Kanie, *A. Muramatsu (Tohoku Univ., Sendai, JP) [119] Abstract

A6.5   16:40   Heterogeneous hydrosilylation of imines using immobilized bis(indenyl)-titanocenes. *H. Gruber-Woelfler, G. J. Lichtenegger, E. Polo1, J. G. Khinast (Graz Univ. Technol., AT; 1Univ. Ferrara, IT) [229] Abstract

A6.6   17:00   Heterogeneously-catalyzed oxidation of ρ-cymene. *M. Golets, A. Samikannu, J.-P. Mikkola1 (Umea Univ., SE; 1Abo Akad. Univ., Turku, FI) [230] Abstract

A6.7   17:20   Effect of addition of a second metal in Mo/ZSM-5 catalyst for methane aromatization reaction under elevated pressures. *M. Bernauer, V. Fila1, Z. Sobalik (Heyrovsky Inst. Phys. Chem., Praha, CZ; 1Inst. Chem. Technol., Praha, CZ) [615] Abstract

A6.8   17:40   Optimization of Pt catalyst for selective nitrostyrene hydrogenation. *A. Yarulin, C. Berguerand, I. Yuranov, F. Cárdenas-Lizana, A. Olasolo Alonso, A. Piloiu, L. Kiwi-Minsker (EPFL, Lausanne, CH) [725] Abstract

A6.9   18:00   A comparison of the hydrothermal and reflux techniques for synthesis of the V2O5 over graphene catalysts utilized in the ODHP reaction. M. Fattahi, *M. Kazemeini, F. Khorasheh, A. M. Rashidi1 (Sharif Univ. Technol., Tehran, IR; 1Nanotechnology Res. Cent. Tehran, IR) [43] Abstract

A7 - Wednesday morning
Reaction engineering, catalysis and kinetics

Kinetics

Chairpersons: O. Jogunola, M. Přibyl

A7.1     8:30   Keynote lecture: Theoretical and experimental studies on local electrochemical kinetics. *M. Přibyl, D. Šnita (Inst. Chem. Technol., Praha, CZ) [812] Abstract

A7.2     9:10   Kinetic peculiarities of selective hydrogenation of 2-methyl-3-butyn-2-ol in batch mode using polymer-based Pd-containing catalysts. *L. Z. Nikoshvili, A. S. Makarova, N. A. Lyubimova, I. Y. Tyamina, E. M. Sulman (Tver State Tech. Univ., RU) [150] Abstract

A7.3     9:30   Computer-assisted development of thermodynamically consistent detailed heterogeneous kinetic mechanisms. *I. I. Mitrichev, A. V. Jensa, E. M. Koltsova (Mendeleev Univ. Chem. Technol. Russia, Moskva, RU) [580] Abstract

A7.5     9:50   Inhibition effect of nitrogen species on reaction rate of diesel fraction hydrodesulphurization. *A. Vráblík, M. Zbuzek, R. Černý, V. Tukač1, A. Prokešová1 (Res. Inst. Inorg. Chem., Litvínov, CZ; 1Inst. Chem. Technol., Praha, CZ) [678] Abstract

10:10   Coffee break, poster session

A7.6   11:00   Characterization of kinetics in chemical looping combustion using NiO/NiAl2O4 tablets in a continuous stirred-tank reactor. *A. Tilland, L. Franck-Lacaze, E. Schaer (Univ. Lorraine, Nancy, FR) [1037] Abstract

A7.7   11:20   Complexation equilibria studies of alkyl formate hydrolysis using butyllimidazole. *O. Jogunola, T. Salmi, J.-P. Mikkola1 (Abo Akad. Univ., Turku, FI; 1Umea Univ., SE) [1090] Abstract

A7.8   11:40   Kinetic modelling of sorbitol aqueous phase reforming. *A. Kirilin, A. Tokarev, J. Wärnå, T. Salmi, D. Y. Murzin (Abo Akad. Univ., Turku, FI) [1342] Abstract

A7.9   12:00   Sulphite oxidation kinetics at low sulphite concentration. *M. Opletal, J. Šíma, M. Kordač (Inst. Chem. Technol., Praha, CZ) [860] Abstract

A7.10   12:20   Kinetics of an electrochemical reaction in microfluidic cell. *M. Nebyla1, V. Vodrážka, P. Beránek1, N. Patel, M. Přibyl1 (Inst. Chem. Technol., Praha, CZ; 1Univ. West Bohemia, Plzeň, CZ) [1041] Abstract

A8 - Wednesday afternoon
Reaction engineering, catalysis and kinetics

Catalysis

Chairpersons: Z. Grof, M. Králik

A8.1   14:00   Evaluation of the applicability of various silica based heterogeneous Pd-catalysts for cross-coupling reactions in packed bed continuous flow reactors. *G. J. Lichtenegger, H. Gruber-Woelfler, J. G. Khinast (Graz Univ. Technol., AT) [838] Abstract

A8.2   14:20   Synthesis and characterization of gallium-promoted copper–ceria catalyst and its application for steam methanol reforming in packed bed reactor. *A. Pohar, S. Hočevar, B. Likozar1, J. Levec1 (Nat. Inst. Chem., Ljubljana, SI; 1Univ. Ljubljana, SI) [931] Abstract

A8.3   14:40   Catalyst deactivation in liquid phase hydrogenations. *M. Králik, M. Turáková1, I. Mačák, P. Lehocký, J. Balko (VUCHT, Bratislava, SK; 1Slovak Univ. Technol., Bratislava, SK) [1004] Abstract

A8.4   15:00   Synthesis of dimethyl carbonate from urea and methanol over novel catalysts. *Z. Zhang, X. Sun, X. Zhang1, W. Sun1, X. Fang1 (East China Univ. Sci. Technol., Shanghai, CN; 1Fushun Res. Inst. Petrol. Petrochem., CN) [1160] Abstract

15:20   Coffee break, poster session

A8.5   16:20   FeCr alloy fluidized bed reactor in miniplant scale for oxidative coupling of methane by Na2WO4-Mn/SiO2 catalytic system. *S. Sadjadi, U. Simon1, H. Godini, O. Görke1, G. Wozny (Tech. Univ., Berlin, DE; 1Inst. Werkstoffwissen. Technol., Berlin, DE) [1333] Abstract

A8.6   16:40   Effect of the calcination temperature of Ni/La2O3–alphaAl2O3 catalyst on its kinetic behaviour in ethanol steam reforming for H2 production. *C. Montero, L. Oar-Arteta, B. Valle Pascual, J. Bilbao, A. G. Gayubo Cazorla (Univ. Pais Vasco, Bilbao, ES) [432] Abstract


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